Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 3 - Review Questions - Page 150: 8

Answer

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Work Step by Step

Resonance occurs when more than one valid Lewis structure can be drawn for a molecule or ion, differing only in the placement of electrons while the arrangement of atoms remains the same. In such cases, the actual structure of the substance is not represented by any single Lewis structure but rather by a resonance hybrid, which is an average of all the possible resonance forms. This happens because certain electrons, particularly π electrons or lone pairs, are delocalized, meaning they are not confined to one bond or atom but are spread over several atoms in the molecule. The delocalization of electrons helps to stabilize the molecule and explains why all bonds in resonance systems often have equal lengths and strengths. We draw resonance structures to show the various possible distributions of electrons and to better represent the true, delocalized nature of bonding that cannot be captured by a single Lewis structure.
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