Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 2 - Integrative Problems - Page 99j: 173

Answer

a. $265$ nm b. Yes c. Copper

Work Step by Step

a. To find the wavelength of the photon needed to eject an electron, we can use the equation: \[ \lambda = \frac{hc}{E} \] Where: \( \lambda \) = wavelength of the photon \( h \) = Planck's constant (\( 6.626 \times 10^{-34} \mathrm{~J\cdot s} \)) \( c \) = speed of light in a vacuum (\( 3.00 \times 10^{8} \mathrm{~m/s} \)) \( E \) = energy of the photon The energy of the photon needed to eject an electron is equal to the work function of the hull, so \( E = 7.52 \times 10^{-19} \mathrm{~J} \). Plugging in the values, we get: \[ \lambda = \frac{(6.626 \times 10^{-34} \mathrm{~J\cdot s})(3.00 \times 10^{8} \mathrm{~m/s})}{7.52 \times 10^{-19} \mathrm{~J}} \] Solving for \( \lambda \), we find: \[ \lambda \approx 2.65 \times 10^{-7} \mathrm{~m} \] So, the wavelength of the photon needed to eject an electron is approximately \( 265 \mathrm{~nm} \). b. The given photon torpedo has a wavelength of \( 259 \mathrm{~nm} = 259 \times 10^{-9} \mathrm{~m} \). Comparing this to the wavelength we calculated in part a ($259<265$), we find that the given photon torpedo has sufficient energy to eject an electron. So, yes, 259-nm electromagnetic radiation will eject an electron. c. The element with an electron configuration of copper (Cu).
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