Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 2 - Exercises - Page 99f: 119

Answer

a. C and Br b. N and Ar c. C and Br

Work Step by Step

a. Nitrogen has a half-filled 2p subshell, making it less eager to accept an extra electron. Carbon’s electron affinity is more negative. Argon is a noble gas with a full shell and essentially zero electron affinity. Bromine, a halogen, has a strong tendency to gain an electron. b. Nitrogen has a higher nuclear charge and a more stable half-filled 2p orbital, requiring more energy to remove an electron. Argon has a full outer shell, making it very stable and harder to ionize. c. Carbon is slightly larger because it has a lower nuclear charge than nitrogen, resulting in less pull on its electrons. Bromine is in Period 4, while Argon is in Period 3. Atomic size increases down a group.
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