Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 2 - Exercises - Page 99d: 77

Answer

See here: - \(5p\) has 1 orbital. - \(3d_{z^{2}}\) has 1 orbital. - \(4d\) has 5 orbitals. - \(n = 5\) has 50 orbitals. - \(n = 4\) has 32 orbitals.

Work Step by Step

Let's analyze each designation: 1. \(5p\): For the \(5p\) designation, \(n = 5\) and \(l = 1\). Since \(l = 1\), there is only one p orbital. Therefore, there is only one orbital with the designation \(5p\). 2. \(3d_{z^{2}}\): For the \(3d_{z^{2}}\) designation, \(n = 3\) and \(l = 2\). Since \(l = 2\), there are five d orbitals. However, the subscript \(z^{2}\) indicates a specific orientation of the d orbital along the z-axis. This means that only one of the five d orbitals has this specific orientation. Therefore, there is only one orbital with the designation \(3d_{z^{2}}\). 3. \(4d\): For the \(4d\) designation, \(n = 4\) and \(l = 2\). Since \(l = 2\), there are five d orbitals. Therefore, there are five orbitals with the designation \(4d\). 4. \(n = 5\): The designation \(n = 5\) represents all the orbitals in the fifth energy level. To determine the number of orbitals, we need to know the maximum number of orbitals in a given energy level. The maximum number of orbitals in an energy level is given by \(2n^2\). For \(n = 5\), the maximum number of orbitals is \(2 \times 5^2 = 50\). Therefore, there are 50 orbitals with the designation \(n = 5\). 5. \(n = 4\): Similarly, the designation \(n = 4\) represents all the orbitals in the fourth energy level. The maximum number of orbitals in this energy level is \(2 \times 4^2 = 32\). Therefore, there are 32 orbitals with the designation \(n = 4\).
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