Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 2 - Exercises - Page 99c: 52

Answer

No

Work Step by Step

To determine if light with a wavelength of \( 225 \mathrm{~nm} \) is capable of ionizing a gold atom, we can use the relationship between energy and wavelength given by the equation: \[ E = \frac{{hc}}{{\lambda}} \] where: - \( E \) is the energy of the light, - \( h \) is Planck's constant (\( 6.626 \times 10^{-34} \) J s), - \( c \) is the speed of light (\( 3.00 \times 10^8 \) m/s), - \( \lambda \) is the wavelength of the light. Substituting the given values: \[ E = \frac{{(6.626 \times 10^{-34} \mathrm{~J\cdot s})(3.00 \times 10^8 \mathrm{~m/s})}}{{225 \times 10^{-9} \mathrm{~m}}} \] \[ E \approx 8.81 \times 10^{-19} \mathrm{~J} \] Now, we convert this energy into kilojoules per mole to compare it with the ionization energy of gold: \[ 8.81 \times 10^{-19} \mathrm{~J} \times \frac{{1 \mathrm{~kJ}}}{{1000 \mathrm{~J}}} \times \frac{{6.022 \times 10^{23} \mathrm{~atoms}}}{{1 \mathrm{~mol}}} \] \[ \approx 530.5 \mathrm{~kJ/mol} \] The energy of the light is much lower than the ionization energy of gold (\( 890.1 \mathrm{~kJ/mol} \)). Therefore, light with a wavelength of \( 225 \mathrm{~nm} \) is not capable of ionizing a gold atom in the gas phase.
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