Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 18 - Ionic Equilibria I: Acids and Bases - Exercises - The Autoionization of Water - Page 743: 13

Answer

6(a) $$[OH^-] = 2.2 \times 10^{-14} \space M$$ 7(b) $$[OH^-] =9.5 \times 10^{-13} \space M$$ 9(c) $$[OH^-] =3.0 \times 10^{-14} \space M$$ --- All these concentrations are lower than $[OH^-] = 1.0 \times 10^{-7}$, which makes sense, since they are all solutions made of acidic compounds, and therefore, acidic solutions.

Work Step by Step

6(a) HBr is a strong acid: $[H_3O^+] = 0.45 M$ $$[OH^-] = \frac{1.0 \times 10^{-14}}{[H_3O^+]} = \frac{1.0 \times 10^{-14}}{ 0.45 } = 2.2 \times 10^{-14} \space M$$ 7(b) According to the calculation we made: $[H_3O^+] = 0.0105 M$ $$[OH^-] = \frac{1.0 \times 10^{-14}}{[H_3O^+]} = \frac{1.0 \times 10^{-14}}{ 0.0105 } = 9.5 \times 10^{-13} \space M$$ 9(c) According to the calculation we made: $[H_3O^+] = 0.336 M$ $$[OH^-] = \frac{1.0 \times 10^{-14}}{[H_3O^+]} = \frac{1.0 \times 10^{-14}}{ 0.336 } = 3.0 \times 10^{-14} \space M$$ --- All these concentrations are lower than $[OH^-] = 1.0 \times 10^{-7}$, which makes sense, since they are all solutions made of acidic compounds, and therefore, acidic solutions.
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