Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 17 - Chemical Equilibrium - Exercises - Calculation of K - Page 702: 29

Answer

$K_c \neq Q_c$, therefore, the system is not at equilibrium. $Q_c \gt K_c$ therefore, the concentration of $NO_2$ will increase as the system proceeds to equilibrium.

Work Step by Step

- Calculate all the concentrations: $$[NO_2] = ( 2.0 \times 10^{-3} )/(10.0) = 2.0 \times 10^{-4} M$$ $$[N_2O_4] = ( 1.5 \times 10^{-3} )/(10.0) = 1.5 \times 10^{-4} M$$ - The exponent of each concentration is equal to its balance coefficient. $$Q_C = \frac{[Products]}{[Reactants]} = \frac{[ N_2O_4 ]}{[ NO_2 ] ^{ 2 }}$$ 2. Substitute the values and calculate the constant value: $$Q_C = \frac{( 1.5 \times 10^{-4} )}{( 2.0 \times 10^{-4} )^{ 2 }} = 4.0 \times 10^{3}$$ $K_c \neq Q_c$, therefore, the system is not at equilibrium. $Q_c \gt K_c$ therefore, there is too much product, so the concentration of $NO_2$ will increase as the system proceeds to equilibrium.
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