Answer
$$\frac{{2\sqrt 3 }}{3},{\text{ }} - \frac{{\sqrt 3 }}{9}$$
Work Step by Step
$$\eqalign{
& {\text{Let }}x = \sec t,{\text{ }}y = \tan t,{\text{ }}t = \pi /3 \cr
& {\text{From the equation }}\frac{{dy}}{{dx}} = \frac{{dy/dt}}{{dx/dt}}{\text{ we have,}} \cr
& \frac{{dy}}{{dt}} = \frac{d}{{dt}}\left[ {\tan t} \right] = {\sec ^2}t \cr
& \frac{{dx}}{{dt}} = \frac{d}{{dt}}\left[ {\sec t} \right] = \sec t\tan t \cr
& \cr
& \frac{{dy}}{{dx}} = \frac{{dy/dt}}{{dx/dt}} = \frac{{{{\sec }^2}t}}{{\sec t\tan t}} \cr
& \frac{{dy}}{{dx}} = \frac{{\sec t}}{{\tan t}} \cr
& \frac{{dy}}{{dx}} = \csc t \cr
& {\text{Evaluate at }}t = \pi /3 \cr
& {\left. {\frac{{dy}}{{dx}}} \right|_{t = \pi /3}} = \csc \left( {\frac{\pi }{3}} \right) \cr
& {\left. {\frac{{dy}}{{dx}}} \right|_{t = \pi /3}} = \frac{{2\sqrt 3 }}{3} \cr
& \cr
& {\text{Where }}\frac{{{d^2}y}}{{d{x^2}}} = \frac{{dy'/dt}}{{dx/dt}},{\text{ and }}y' = \frac{{{{\sec }^2}t}}{{\sec t}} = \csc t \cr
& \frac{{dy'}}{{dt}} = \frac{d}{{dt}}\left[ {\csc t} \right] \cr
& \frac{{dy'}}{{dt}} = - \csc t\cot t \cr
& {\text{Therefore}} \cr
& \frac{{{d^2}y}}{{d{x^2}}} = \frac{{ - \csc t\cot t}}{{\sec t\tan t}} = - \frac{{{{\cos }^3}t}}{{{{\sin }^3}t}} \cr
& \frac{{{d^2}y}}{{d{x^2}}} = - {\cot ^3}t \cr
& {\text{Evaluate at }}t = \pi /3 \cr
& {\left. {\frac{{{d^2}y}}{{d{x^2}}}} \right|_{t = \pi /3}} = - {\cot ^3}\left( {\frac{\pi }{3}} \right) \cr
& {\left. {\frac{{{d^2}y}}{{d{x^2}}}} \right|_{t = \pi /3}} = {\left( { - \frac{{\sqrt 3 }}{3}} \right)^3} \cr
& {\left. {\frac{{{d^2}y}}{{d{x^2}}}} \right|_{t = \pi /3}} = - \frac{{\sqrt 3 }}{9} \cr} $$