University Physics with Modern Physics (14th Edition)

Published by Pearson
ISBN 10: 0321973615
ISBN 13: 978-0-32197-361-0

Chapter 19 - The First Law of Thermodynamics - Problems - Exercises - Page 640: 19.11

Answer

(a)$T_a = 278.5 K$ (b)$W_{ab} = 0 $ $W_{bc} = 162 J $ (c)$ΔU = 53 J $

Work Step by Step

(a) The lowest temperature is at the point (a). We know it because it has the lowest pressure and volume. $T_a = \frac{p_aV_a}{nR}$ $T_a = \frac{(0.20 atm)(1.013 \times 10^5 Pa/atm)(2.0 L)(1.0 \times 10^{-3} m^3/L)}{(0.0175)(8.314 J/mol.K)}$ $T_a = 278.5 K$ (b) Work done from a to b $W_{ab} = p(\Delta V)$ and in the figure, there is no change in volume so $\Delta V = 0$ $W_{ab} = p(0)$ $W_{ab} = 0 $ Work done from b to c, area under the curve is $W_{bc} = \frac{1}{2} (0.50 atm + 0.30 atm)(6.0 L − 2.0 L) $ $W_{bc} = (1.6 atm. L) (1.013 \times 10^5 Pa/atm)(1.0 \times 10^{-3} m^3/L)$ $W_{bc} = 162 J $ (c) The internal energy is $ΔU = Q −W$ $ΔU = 215 J - 162 J $ $ΔU = 53 J $
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