Answer
a) $13.6eV$
b) $\Delta E=10.2eV$
Work Step by Step
(a) We know that the total energy possessed by an electron of hydrogen atom in the ground state is $-13.6eV$, therefore, the highest-energy photon this system can absorb without dissociating the electron from the proton is just below $13.6eV$.
(b) We know that
$\Delta E=E_2-E_1$
We plug in the known values to obtain:
$\Delta E=\frac{-13.6}{2^2}-\frac{-13.6}{1^2}$
$\Delta E=10.2eV$