Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 6 - Electronic Structure of Atoms - Additional Exercises - Page 254: 6.102f

Answer

The condensed electron configuration of $Sg$ is $$Sg:[Rn]5f^{14}6d^{4}7s^2$$ There are 4 unpaired electrons.

Work Step by Step

1) The nearest noble gas of lower atomic number of $Sg$ is $Rn$. 2) Looking the periodic table, the atomic number of $Sg$ is 106, which means it has 106 electrons. The last row ends with the atomic number 86, so $Sg$ has 86 inner-shell electrons. That leaves it with 20 outer-shell electrons. $Sg$ belongs to the 7th row, so its outer shell is the 7th shell. 3) These 20 outer-shell electrons are distributed as follows: - The first two go to the $7s$ subshell. - The next 14 go to the $5f$ subshell. - The last 4 go to the $6d$ subshell. Therefore, the condensed electron configuration of $Sg$ is $$Sg:[Rn]5f^{14}6d^{4}7s^2$$ 4) All the inner shells, the $7s$ subshell, the $5f$ subshell are completely filled, so all of their electrons are paired. There are 4 electrons in subshell $6d$, and subshell $6d$ has 5 orbitals. According to Hund's rule, these 4 electrons each occupies a different orbital. In the end, there are 4 one-electron orbitals. Therefore, there are 4 unpaired electrons.
Update this answer!

You can help us out by revising, improving and updating this answer.

Update this answer

After you claim an answer you’ll have 24 hours to send in a draft. An editor will review the submission and either publish your submission or provide feedback.