Chemistry 9th Edition

Published by Cengage Learning
ISBN 10: 1133611095
ISBN 13: 978-1-13361-109-7

Chapter 16 - Solubility and Complex-Ion Equilibria - Exercises - Page 781: 23

Answer

$ K_{sp} (Ni(OH)_2)(20^{\circ}C) = (1.4 \times 10^{-8})$

Work Step by Step

1. Calculate the molar mass: 58.69* 1 + 2 * ( 16* 1 + 1.01* 1 ) = 92.71g/mol 2. Calculate the number of moles $n(moles) = \frac{mass(g)}{mm(g/mol)}$ $n(moles) = \frac{ 0.14}{ 92.71}$ $n(moles) = 1.51\times 10^{- 3}$ 3. Find the concentration in mol/L: $1.51 \times 10^{-3}$ mol in 1L: $1.51 \times 10^{-3} M$ 4. Write the $K_{sp}$ expression: $ Ni(OH)_2(s) \lt -- \gt 1Ni^{2+}(aq) + 2{OH}^{-}(aq)$ $ K_{sp} = [Ni^{2+}]^ 1[{OH}^{-}]^ 2$ 5. Determine the ions concentrations: $[Ni^{2+}] = [Ni(OH)_2] * 1 = [1.51 \times 10^{-3}] * 1 = 1.51 \times 10^{-3}$ $[{OH}^{-}] = [Ni(OH)_2] * 2 = 3.02 \times 10^{-3}$ 6. Calculate the $K_{sp}$: $ K_{sp} = (1.51 \times 10^{-3})^ 1 \times (3.02 \times 10^{-3})^ 2$ $ K_{sp} = (1.51 \times 10^{-3}) \times (9.121 \times 10^{-6})$ $ K_{sp} = (1.377 \times 10^{-8}) \approx 1.4 \times 10^{-8}$
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