Chemistry 9th Edition

Published by Cengage Learning
ISBN 10: 1133611095
ISBN 13: 978-1-13361-109-7

Chapter 16 - Solubility and Complex-Ion Equilibria - Exercises - Page 781: 25

Answer

$ K_{sp} (PbBr_2) = (3.92 \times 10^{-5})$

Work Step by Step

1. Write the $K_{sp}$ expression: $ PbBr_2(s) \lt -- \gt 1Pb^{2+}(aq) + 2{Br}^{-}(aq)$ $ K_{sp} = [Pb^{2+}]^ 1[{Br}^{-}]^ 2$ 2. Determine the ions concentrations: $[Pb^{2+}] = [0.0214] $ $[{Br}^{-}] = [Pb^{2+}] * 2 = 0.0428$ ** Considering a pure solution. 3. Calculate the $K_{sp}$: $ K_{sp} = (0.0214)^ 1 \times (0.0428)^ 2$ $ K_{sp} = (0.0214) \times (1.832 \times 10^{-3})$ $ K_{sp} = (3.92 \times 10^{-5})$
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