Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 13 - Chemical Kinetics - Questions & Problems - Page 609: 13.7

Answer

(a) 0.066 M/s (b) -0.033 M/s

Work Step by Step

From the reaction, rate of the reaction, $ R$ is $$ R = \frac{-d[NO]}{2dT} = \frac{-d[O_2]}{dT} = \frac{d[NO_2]}{2dT}$$ It is given that $$ \frac{-d[NO]}{dT} = 0.066 M/s$$ Therefore, $$ R= \frac{0.066}{2} = 0.033 M/s$$ (a) Rate of formation of $NO_2$ is given by $$\frac{d[NO_2]}{dT} = 2\times R = 2\times0.033 M/s = 0.066 M/s$$ (b) Rate of reaction of molecular oxygen is given by, $$ \frac{d[O_2]}{dT} = -R = -0.033 M/s $$
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