Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 18 - The Micro/Macro Connection - Exercises and Problems - Page 524: 56

Answer

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Work Step by Step

Let's assume that each degree of freedom will contribute $\frac{1}{2} R$ to the molar-specific heat. In a two-dimensional lattice, the motion of an atom is confined to two directions, hence the compression or stretching of molecular bonds occurs in two dimensions as well. This yields 4 degrees of freedom which means that the molar-specific heat of graphene might be $2R$. The atoms can also move slightly out of the plane, which adds another degree of freedom, and this out-of-plane motion induces bond stretching in a new manner, adding another degree of freedom. Thus there are more than 4 degrees of freedom. Recalling that the actual value of the molar-specific heat of graphene is 23.5 J/mol K which means that there are between 5 to 6 degrees of freedom, Not only 4.
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