Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 17 - Radioactivity and Nuclear Chemistry - Exercises - Cumulative Problems - Page 640: 94

Answer

1.14 $\times$ $10^{20}$ no. of alpha emission will occur in 6.0 minutes.

Work Step by Step

Half life of Po-218 given = 3.0 minutes That means, in 3.0 minutes half of initial amount of Po left. Here, Initial amount = 55 mg Amount of Po left in 3.0 minutes = $\frac{55}{2}$ mg Hence, Amount of Po left in 6.0 minutes = $\frac{55}{4}$ = 13.75 mg Therefore, Amount of Po that has been disintegrated in 6.0 minutes = (55-13.75) = 41.25 mg = 41.25 $\times$ $10^{-3}$ g Now, Atomic mass of Po-218 = 218 amu (approx) 1 mole Po = 218 g Po Hence, 218 g Po contains 6.023 $\times$ $10^{23}$ no. of Po atoms Therefore, 41.25 $\times$ $10^{-3}$ g Po will contain $\frac{6.023 \times10^{23}\times41.25 \times10^{-3} }{218}$ $\approx$ 1.14 $\times$ $10^{20}$ no. of Po which will be disintegrated and emit same no. of alpha particle. Answer: 1.14 $\times$ $10^{20}$ alpha emission will occur in 6.0 minutes.
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