Chemistry: The Molecular Nature of Matter and Change 7th Edition

Published by McGraw-Hill Education
ISBN 10: 007351117X
ISBN 13: 978-0-07351-117-7

Chapter 17 - Problems - Page 770: 17.37

Answer

The reaction proceeds to the left.

Work Step by Step

- $\Delta n = 2-2 = 0$ Therefore: $K_p = K_c$ and $Q_p = Q_c$ $K_c = 2.7$ Calculate $Q_c$: 1. The exponent of each concentration is equal to its balance coefficient. $$Q_C = \frac{[Products]}{[Reactants]} = \frac{[ CO_2 ][ H_2 ]}{[ CO ][ H_2O ]} = \frac{\frac{n_{CO_2}}{V}\frac{n_{H_2}}{V}}{\frac{n_{CO}}{V}\frac{n_{H_2O}}{V}} = \frac{n_{CO_2}n_{H_2}}{n_{CO}n_{H_2O}} $$ 2. Substitute the values and calculate the quotient value: $$Q_C = \frac{( 0.62 )( 0.43 )}{( 0.13 )( 0.56 )} = 3.7$$ Since $Q_c \gt K_c$, the reaction will proceed to the left. (reactants side)
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