Answer
47/52
Work Step by Step
There are $\binom{52}{5} = \frac{52!}{47! 5!} = 2,598,960$ possible five-card poker hands. If the queen of hearts cannot be draw, there are $\binom{51}{5} = \frac{51!}{46! 5!}$ such hands. Thus the probability is
$$\frac{51!}{46!5!}\frac{47!5!}{52!} = 47/52$$