Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Foundations - Topic A - Matter - Exercises - Page 23: A.19(a)

Answer

Molecular formula of sulfur is S8

Work Step by Step

from Ideal gas law: PV = nRT P = 93.2 kPa (0.9198125 atm) R: gas constant (0.0821 L-atm / mole-K) T: gas temperature in Kelvin (293.15) , but n = m/M .........m: is mass of gas........... M: molar mass of gas PV = (m/M) RT MPV =mRT ..................... M= (m/V)(RT/P) m/V = d, while d is denisty of gas (mass/volume) so M = (dRT)/P = 3.710 × 0.0821 × 773.15 / 0.9198125 = 256 g n of gas = Mass of gas / Molar mass of sulfur = 256/16 = 8
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