Materials Science and Engineering: An Introduction

Published by Wiley
ISBN 10: 1118324579
ISBN 13: 978-1-11832-457-8

Chapter 14 - Polymer Structures - Questions and Problems - Page 579: 14.27

Answer

$J = 2.71 \times 10^{-6} \frac{cm^{3}STP}{cm^{2}-s}$

Work Step by Step

Given: Consider the diffusion of oxygen through a low density polyethylene (LDPE) sheet 15 mm thick. The pressures of oxygen at the two faces are 2000 kPa ($2.0 \times 10^{6} Pa$) and 150 kPa (150,000 Pa), which are maintained constant. Required: The diffusion flux (in $(cm^{3} STP/cm^{2})$ at 298 K, assuming steady state conditions. Solution: Using Equation 14.9 and using the permeability coefficient of oxygen through LDPE in Table 14.6, it follows: $2.2 \times 10^{-13} (cm^{3} STP)-cm/cm^{2}-s-Pa$, $J = P_{M} \frac{ΔP}{Δx} = P_{M} \frac{P_{2}-P_{1}}{Δx} = (\frac {2.2 \times 10^{-13} (cm^{3} STP)-cm}{cm^{2}-s-Pa}) \frac{(2.0 \times 10^{6} Pa) -150,000 Pa}{0.15 cm} \\= 2.71 \times 10^{-6} \frac{cm^{3}STP}{cm^{2}-s}$
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