Pi launched the film scoring career of Clint Mansell. The soundtrack was released on July 21, 1998 via Sire label. Allmusic rated it 4.5 stars out of five.[10] A music video for "πr²", using an alternative mix of the title track, is available as a special feature on the π DVD, consisting of footage from the film intercut with stock color reels of ants, harking back to one of the film's visual motifs.

No. Title Artist Length
1. "πr²"   Clint Mansell 1:29
2. "P.E.T.R.O.L."   Orbital 6:22
3. "Kalpol Introl" (The back cover incorrectly names track 3 as "Kalpol Intro".) Autechre 3:30
4. "Bucephalus Bouncing Ball"   Aphex Twin 6:02
5. "Watching Windows" (Ed Rush & Optical remix) Roni Size 6:35
6. "Angel"   Massive Attack 6:10
7. "We Got the Gun"   Clint Mansell 4:52
8. "No Man's Land"   David Holmes 6:18
9. "Anthem"   GusGus 4:52
10. "Drippy"   Banco de Gaia 8:37
11. "Third from the Sun"   Psilonaut 5:10
12. "A Low Frequency Inversion Field"   Spacetime Continuum 6:58
13. "2πr"   Clint Mansell 3:05
  • Design – Jeremy Dawson, Sneak Attack
  • Executive-Producer – Eric Watson, Ricardo Vinas, Sioux Zimmerman
  • Mastered By – Mark Fellows
  • Written-By [Voiceover] – Darren Aronofsky, Sean Gullette

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