- Abhishek Bachchan as Gurukant "Guru" Desai
- Aishwarya Rai as Sujata "Suju" Desai
- Mithun Chakraborty as "Nanaji" Manik Dasgupta
- R. Madhavan as Shyam Saxena
- Vidya Balan as Meenakshi "Meenu" Saxena (née Gupta)
- Roshan Seth as Justice Thapar
- Mallika Sherawat in a guest appearance as Champa, the dancer in song "Mayya Mayya"
- Arya Babbar as Jignesh
- Arjan Bajwa as Arzan Contractor
- Rajendra Gupta as Guru's father Kantilal Desai
- Sarita Joshi as Guru's stepmother
- Sachin Khedekar as Sujata's father
- Sudhir Pandey as Mathura Das
- Neena Kulkarni as Tulsiben, Sujata's mother
- Prathap K. Pothan as K. R. Menon I.A.S.
- Darshan Jariwala as cashier Anand Palekar
- Sanjay Mishra as Chhagan, Guru's senior in Turkey
- Manoj Joshi as Ghanshyam Das
- Dhritiman Chatterjee as Contractor
- Sanjay Swaraj as Guru's brother
- T. M. Karthik as Doctor
- Anaushka Dantra and Ashoi Dantra as Disha Desai and Drishti Desai, Guru's twin daughters
- Sunil Agarwal as Ashok Agarwal
- Murad Ali
- Raviprakash as Bhanu Patel (in voice)
- Sunny Subramanian as Young Guru
- Mukesh S Bhatt as Ramlal
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