General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 7 - Chemical Reactions and Quantities - Challenge Questions - Page 285: 7.151

Answer

a. 3.38 moles of $O_2$ b. 36.2 g of $Cr_2O_3$ c. 25.3 g of $Cr_2O_3$ d. Percent yield = 80.8 %

Work Step by Step

a. $$ 4.50 \space moles \space Cr \times \frac{ 3 \space moles \ O_2 }{ 4 \space moles \space Cr } = 3.38 \space moles \space O_2 $$ b. $ Cr $ : 52.00 g/mol $$ \frac{1 \space mole \space Cr }{ 52.00 \space g \space Cr } \space and \space \frac{ 52.00 \space g \space Cr }{1 \space mole \space Cr }$$ $ Cr_2O_3 $ : ( 52.00 $\times$ 2 )+ ( 16.00 $\times$ 3 )= 152.00 g/mol $$ \frac{1 \space mole \space Cr_2O_3 }{ 152.00 \space g \space Cr_2O_3 } \space and \space \frac{ 152.00 \space g \space Cr_2O_3 }{1 \space mole \space Cr_2O_3 }$$ $$ 24.8 \space g \space Cr \times \frac{1 \space mole \space Cr }{ 52.00 \space g \space Cr } \times \frac{ 2 \space moles \space Cr_2O_3 }{ 4 \space moles \space Cr } \times \frac{ 152.00 \space g \space Cr_2O_3 }{1 \space mole \space Cr_2O_3 } = 36.2 \space g \space Cr_2O_3 $$ c. - Calculate or find the molar mass for $ Cr $: $ Cr $ : 52.00 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 26.0 \space g \times \frac{1 \space mole}{ 52.00 \space g} = 0.500 \space mole$$ - Calculate or find the molar mass for $ O_2 $: $ O_2 $ : ( 16.00 $\times$ 2 )= 32.00 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 8.00 \space g \times \frac{1 \space mole}{ 32.00 \space g} = 0.250 \space mole$$ Find the amount of product if each reactant is completely consumed. $$ 0.500 \space mole \space Cr \times \frac{ 2 \space moles \ Cr_2O_3 }{ 4 \space moles \space Cr } = 0.250 \space mole \space Cr_2O_3 $$ $$ 0.250 \space mole \space O_2 \times \frac{ 2 \space moles \ Cr_2O_3 }{ 3 \space moles \space O_2 } = 0.1667 \space mole \space Cr_2O_3 $$ Since the reaction of $ O_2 $ produces less $ Cr_2O_3 $ for these quantities, it is the limiting reactant. - Calculate or find the molar mass for $ Cr_2O_3 $: $ Cr_2O_3 $ : 152.00 g/mol - Using the molar mass as a conversion factor, find the mass in g: $$ 0.1667 \space mole \times \frac{ 152.00 \space g}{1 \space mole} = 25.3 \space g$$ d. - Find the theoretical yield: - Calculate or find the molar mass for $ Cr $: $ Cr $ : 52.00 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 74.0 \space g \times \frac{1 \space mole}{ 52.00 \space g} = 1.42 \space moles$$ - Calculate or find the molar mass for $ O_2 $: $ O_2 $ : ( 16.00 $\times$ 2 )= 32.00 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 62.0 \space g \times \frac{1 \space mole}{ 32.00 \space g} = 1.94 \space moles$$ Find the amount of product if each reactant is completely consumed. $$ 1.42 \space moles \space Cr \times \frac{ 2 \space moles \ Cr_2O_3 }{ 4 \space moles \space Cr } = 0.710 \space mole \space Cr_2O_3 $$ $$ 1.94 \space moles \space O_2 \times \frac{ 2 \space moles \ Cr_2O_3 }{ 3 \space moles \space O_2 } = 1.29 \space moles \space Cr_2O_3 $$ Since the reaction of $ Cr $ produces less $ Cr_2O_3 $ for these quantities, it is the limiting reactant. - Calculate or find the molar mass for $ Cr_2O_3 $: $ Cr_2O_3 $ : ( 52.00 $\times$ 2 )+ ( 16.00 $\times$ 3 )= 152.00 g/mol - Using the molar mass as a conversion factor, find the mass in g: $$ 0.710 \space mole \times \frac{ 152.00 \space g}{1 \space mole} = 108 \space g$$ - Calculate the percent yield: $$\frac{87.3 \space g \space Cr_2O_3}{108 \space g \space Cr_2O_3} \times 100\% = 80.8 \%$$
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