General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 7 - Chemical Reactions and Quantities - Additional Questions and Problems - Page 284: 7.143

Answer

a. 4.51 kJ are required to produce 3.00 g of NO b. This is the complete equation for the decomposition of NO: $$2 NO(g) \longrightarrow N_2(g)+O_2(g)+90.2 \space kJ$$ c. 7.51 kJ are released when 5.00 g of NO decomposes.

Work Step by Step

a. - Find the conversion factors: $ NO $ : ( 14.01 $\times$ 1 )+ ( 16.00 $\times$ 1 )= 30.01 g/mol $$ \frac{1 \space mole \space NO }{ 30.01 \space g \space NO } \space and \space \frac{ 30.01 \space g \space NO }{1 \space mole \space NO }$$ According to the balanced equation: $$ \frac{ 2 \space moles \space NO }{ 90.2 \space kJ} \space and \space \frac{ 90.2 \space kJ}{ 2 \space moles \space NO }$$ - Find the total energy using these conversion factors: $$ 3.00 \space g \space NO \times \frac{1 \space mole \space NO }{ 30.01 \space g \space NO } \times \frac{ 90.2 \space kJ}{ 2 \space moles \space NO } = 4.51 \space kJ$$ b. Since $\Delta H \gt 0$, the reaction is endothermic, thus, the heat will appear in the reactants side: $$N_2(g)+O_2(g)+90.2 \space kJ \longrightarrow 2 NO(g)$$ But, this is the reaction for the formation of NO. If we want to write the reaction for the decomposition of NO, we can just reverse the equation: $$2 NO(g) \longrightarrow N_2(g)+O_2(g)+90.2 \space kJ$$ c. - Find the conversion factors: $ NO $ : ( 14.01 $\times$ 1 )+ ( 16.00 $\times$ 1 )= 30.01 g/mol $$ \frac{1 \space mole \space NO }{ 30.01 \space g \space NO } \space and \space \frac{ 30.01 \space g \space NO }{1 \space mole \space NO }$$ According to the balanced equation: $$ \frac{ 2 \space moles \space NO }{ -90.2 \space kJ} \space and \space \frac{ -90.2 \space kJ}{ 2 \space moles \space NO }$$ - Find the total energy using these conversion factors: $$ 5.00 \space g \space NO \times \frac{1 \space mole \space NO }{ 30.01 \space g \space NO } \times \frac{ -90.2 \space kJ}{ 2 \space moles \space NO } = -7.51 \space kJ$$ ** Since the heat is now in the products side, it is negative. ** Negative heat = released heat
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