General Chemistry 10th Edition

Published by Cengage Learning
ISBN 10: 1-28505-137-8
ISBN 13: 978-1-28505-137-6

Chapter 12 - Solutions - Questions and Problems - Page 526: 12.14

Answer

The boiling point of a solution containing a non-volatile solute is higher than that of a solution containing a volatile solute because the normal boiling point of a solute is the temperature when the vapor pressure of a solute equals 1 atm. By adding a non-volatile solute to the liquid reduces the vapor pressure of the liquid a higher temperature must be required to achieve 1 atm vapor pressure.

Work Step by Step

The boiling point of a solution containing a non-volatile solute is higher than that of a solution containing a volatile solute because the normal boiling point of a solute is the temperature when the vapor pressure of a solute equals 1 atm. By adding a non-volatile solute to the liquid reduces the vapor pressure of the liquid a higher temperature must be required to achieve 1 atm vapor pressure.
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