Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 7 - Periodic Properties of the Elements - Exercises - Page 292: 7.40b


The statement is false.

Work Step by Step

To find out which one has a larger first ionization energy, we must compare the effective nuclear charge on the outermost electrons of both element to find out which outermost electron undergoes larger attraction from the nucleus. $O$ has a nuclear charge of $8+$ and has 2 inner electrons and 6 outer electrons. $F$ has a nuclear charge of $9+$ and has 2 inner electrons and 7 outer electrons. $F$ obviously has a higher nuclear charge than $O$. In addition, both have the same number of inner electrons. Though $F$ also has more outer electrons than $O$, these outer electrons are not quite effective in shielding the attraction from the nucleus. Therefore, the outer electrons in $F$ experiences a higher attraction from the nucleus than those in $O$ and as a result, harder to be removed. Therefore, the first ionization energy of $F$ would be higher than that of $O$. The statement is false. (Another way to look at this is through the radii of the atoms. $F$ has a smaller radium than $O$, since there is more attraction to the outer electrons from the nucleus, pulling them closer to the nucleus. That means the first ionization energy of $F$ must be higher.)
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