Chemistry and Chemical Reactivity (9th Edition)

Published by Cengage Learning
ISBN 10: 1133949649
ISBN 13: 978-1-13394-964-0

Chapter 17 Principles of Chemical Reactivity: Other Aspects of Aqueous Equilibria - Study Questions - Page 677c: 67

Answer

Since $Q_{sp} \gt K_{sp}$, there will be precipitation of zinc hydroxide.

Work Step by Step

1. Calculate the molar mass $(NaOH)$: 22.99* 1 + 16* 1 + 1.008* 1 = 39.998g/mol 2. Calculate the number of moles $(NaOH)$ $n(moles) = \frac{mass(g)}{mm(g/mol)}$ $n(moles) = \frac{ 0.0040}{ 39.998}$ $n(moles) = 1.0 \times 10^{- 4}$ 3. Find the concentration in mol/L $(NaOH)$: $C(mol/L) = \frac{n(moles)}{volume(L)}$ $ C(mol/L) = \frac{ 1.0\times 10^{- 4}}{ 0.01} $ $C(mol/L) = 0.010$ Since $NaOH$ is 100% ionizated in water, the concentration of $[OH^-]$ is equal to $0.010M$ too. 4. Write the $K_{sp}$ expression: $ Zn(OH)_2(s) \lt -- \gt 1Zn^{2+}(aq) + 2OH^{-}(aq)$ $ K_{sp} = [Zn^{2+}]^ 1[OH^{-}]^ 2$ 5. Find the $Q_{sp}$ value $ Q_{sp} = (1.63 \times 10^{-4})^ 1 \times (0.010)^ 2$ $ Q_{sp} = 1.63 \times 10^{-4} \times (1 \times 10^{-4})$ $ Q_{sp} = 1.63 \times 10^{-8}$ $K_{sp} (Zn(OH)_2) = 3 \times 10^{-17}$ Since $Q_{sp} \gt K_{sp}$, there will be precipitation
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