Chemistry and Chemical Reactivity (9th Edition)

Published by Cengage Learning
ISBN 10: 1133949649
ISBN 13: 978-1-13394-964-0

Chapter 13 Solutions and Their Behavior - 13-5 Colloids - Applying Chemical Principles - Questions - Page 502: 4


$\Delta H_{vap}=34.5\ kJ/mol$

Work Step by Step

From the Clausius-Clapeyron equation: $ln (\dfrac{P_1}{P_2})=\dfrac{-\Delta H_{vap}}{R}\times(\dfrac{1}{T_1}-\dfrac{1}{T_2})$ $ln (\dfrac{760\ mmHg}{361.5\ mmHg})=\dfrac{-\Delta H_{vap}}{8.314\ J/K.mol}\times(\dfrac{1}{(273+98.1)K}-\dfrac{1}{(273+75)K})$ $0.743= \dfrac{-\Delta H_{vap}}{8.314\ J/K.mol}\times-1.789\times10^{-4}$ $\Delta H_{vap}=34534\ J/mol=34.5\ kJ/mol$
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