Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 21 - Metallurgy and the Chemistry of Metals - Questions & Problems - Page 953: 21.14

Answer

The sulfide ore is first roasted in air: $2ZnS(s) + 3O_{2}(g) -> 2ZnO(s) + 2SO_{2}(g)$ The zinc oxide is then mixed with coke and limestone in a blast furnace where the following reductions occur: $ZnO(s) + C(s) -> Zn(g) + CO(g)$ $ZnO(s) + CO(g) -> Zn(g) + CO_{2}(g)$ The zinc vapor formed distills from the furnace into an appropriate receiver.

Work Step by Step

The sulfide ore is first roasted in air: $2ZnS(s) + 3O_{2}(g) -> 2ZnO(s) + 2SO_{2}(g)$ The zinc oxide is then mixed with coke and limestone in a blast furnace where the following reductions occur: $ZnO(s) + C(s) -> Zn(g) + CO(g)$ $ZnO(s) + CO(g) -> Zn(g) + CO_{2}(g)$ The zinc vapor formed distills from the furnace into an appropriate receiver.
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