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Primrose Everdeen, Katniss' sister, is the first name read at the reaping.
The Hunger Games
Primrose Everdeen, Katniss' younger sister. Primrose because in chapter 1 Effie Trinket the escort for the tributes called out her name. The Peacekeepers came and took Prim. Katniss said "I volenteer . I say. I volenteer as tribute."
The Hunger Games ( The first novel of this trilogy.)