Physics Technology Update (4th Edition)

Published by Pearson
ISBN 10: 0-32190-308-0
ISBN 13: 978-0-32190-308-2

Chapter 18 - The Laws of Thermodynamics - Problems and Conceptual Exercises - Page 646: 41

Answer

(a) process 1: $159KJ$; process 2: $1060KJ$ (b) $424KJ$ (c) $795KJ$

Work Step by Step

(a) We can find the required heat added in the two processes as follows: $T_i=\frac{P_iV_i}{nR}$ $\implies T_i=\frac{(106\times 10^3Pa)(1m^3)}{(60mol)(8.31J/mol.K)}$ $T_i=212.6K$ Similarly $T_f=\frac{P_fV_f}{nR}$ $\implies T_i=\frac{(212\times 10^3Pa)(1m^3)}{(60mol)(8.31J/mol.K)}$ $T_i=425.25K$ The heat added in process(1) is given as $Q_v=\frac{3}{2}nR(T_f-Ti)$ We plug in the known values to obtain: $Q_v=\frac{3}{2}(60mol)(8.31J/mol.K)(425.25K-212.6K)$ $Q_v=159KJ$ Now $T_f=\frac{P_fV_f}{nR}$ We plug in the known values to obtain: $T_f=\frac{(212KPa)(3m^3)}{(60mol)(8.31J/mol.K)}$ $T_f=1275.6K$ The heat added in process (2) is given as $Q_p=\frac{5}{2}nR(T_f-T_i)$ We plug in the known values to obtain: $Q_p=\frac{5}{2}(60mol)(8.31J/mol.K)(1275.6K-425.25K)$ $Q_p=1060KJ$ (b) We can find the required work done as follows: $W=P\Delta V$ We plug in the known values to obtain: $W=(212\times 10^3Pa)(3m^3-1m^3)$ $W=424KJ$ (c) We know that $\Delta U=Q_v+Q_p+W$ We plug in the known values to obtain: $\Delta U=159KJ+1060KJ-424KJ$ $\Delta U=795KJ$
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