Physics Technology Update (4th Edition)

Published by Pearson
ISBN 10: 0-32190-308-0
ISBN 13: 978-0-32190-308-2

Chapter 18 - The Laws of Thermodynamics - Problems and Conceptual Exercises - Page 645: 24

Answer

a) $W=13.7KJ$ b) $Q=0$ c) $\Delta U=-13.7JK$

Work Step by Step

(a) We know that $\Delta U=n(\frac{3}{2}R)(T_f-T_i)$ We plug in the known values to obtain: $\Delta U=(3.92mol)(\frac{3}{2})(8.31J/mol.K)(205^{\circ}C-485^{\circ}C)$ $\Delta U=-13.7KJ$ Now $\Delta U=Q-W$ $\implies \Delta U=0-W$ $\implies W=-\Delta U$ $W=-(-13.7KJ)$ $W=13.7KJ$ (b) We know that in an adiabatic process, the system is thermally insulated and no heat flows, so $Q=0$ (c) We know that $\Delta U=Q-W$ $\Delta U=0-W$ $\implies \Delta U=-W$ $\Delta U=-13.7JK$
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