Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 18 - The Micro/Macro Connection - Exercises and Problems - Page 525: 63

Answer

See the detailed answer below.

Work Step by Step

a) The process at which the pressure is directly proportional to the volume of the gas $$P\propto V\tag 1$$ is a straight line with a positive slope since both increase or decrease at the same rate. Now let's assume that the initial situation is $P_i$, $V_i$, $T_i$, and $v_{\rm rms,1}$. Now we need to find the final situation at which the rms speed is doubled. We know that the rms speed is given by $$v_{\rm rms,1}=\sqrt{\dfrac{3k_BT_i}{m}}$$ And we know that the final rms speed is $$v_{\rm rms,2}=2v_{\rm rms,1}=2\sqrt{\dfrac{3k_BT_i}{m}}$$ Hence, $$v_{\rm rms,2} =2\sqrt{\dfrac{3k_BT_i}{m}}$$ $$\sqrt{\dfrac{3k_BT_f}{m}} =2\sqrt{\dfrac{3k_BT_i}{m}}$$ Squaring both sides $$ \dfrac{ \color{red}{\bf\not} 3 \color{red}{\bf\not} k_BT_f}{ \color{red}{\bf\not} m} =(4)\dfrac{ \color{red}{\bf\not} 3 \color{red}{\bf\not} k_BT_i}{ \color{red}{\bf\not} m}$$ Thus, $$T_f=4T_i\tag 2$$ Applying the ideal gas law, $$\dfrac{P_iV_i}{T_i}=\dfrac{P_fV_f}{T_f}$$ Plugging from (2) $$\dfrac{P_iV_i}{ \color{red}{\bf\not} T_i}=\dfrac{P_fV_f}{4 \color{red}{\bf\not} T_i}$$ Hence, $$P_fV_f=4P_iV_i\tag 3$$ From (1), we can see that $$\dfrac{P_i }{P_f}=\dfrac{V_i}{V_f}$$ Solving for $V_i$l $$V_i=\dfrac{P_iV_f}{P_f}$$ Plugging into (3); $$P_f \color{red}{\bf\not} V_f=4P_i \dfrac{P_i \color{red}{\bf\not} V_f}{P_f}$$ $$P_f^2=4P_i^2$$ Hence, $$\boxed{P_f=2P_i}$$ And then the final volume is $$\boxed{V_f=2V_i}$$ This means that the pressure is doubled and the volume is also doubled. See the graph below. __________________________________________________________ b) We know that the change in the thermal energy of the gas is given by $$\Delta E_{th}=Q+W$$ Thus, $$Q=\Delta E_{th}-W$$ where $W=-$Area under the $P-V$ curve, and $\Delta E_{th}=nC_{\rm V}\Delta T$ Hence, $$Q=nC_{\rm V}(T_f-T_i)-{\rm(-Area)}$$ We are given that $C_{\rm V}=\frac{5}{2}R$ $$Q=\frac{5}{2}nR(T_f-T_i)+{\rm(Area)}$$ The area under the curve consists of two things, a right triangle and rectanguale, see the second figure below. $$Q=\frac{5}{2}nR(4T_i-T_i)+\frac{1}{2}(2V_i-V_i)(2P_i-P_i)+P_i(2V_i-V_i)$$ $$Q=\frac{15}{2}nRT_i+ \frac{3}{2}P_iV_i\tag 4$$ Noting that $T_i$ is given by the ideal gas law $$P_iV_i=nRT_i$$ Hence, $$T_i=\dfrac{P_iV_i}{nR}$$ Plugging into (4); $$Q=\frac{15}{2} \color{red}{\bf\not} n \color{red}{\bf\not} R \dfrac{P_iV_i}{ \color{red}{\bf\not} n \color{red}{\bf\not} R}+ \frac{3}{2}P_iV_i $$ $$Q=\frac{15}{2} P_iV_i + \frac{3}{2}P_iV_i $$ $$\boxed{Q=9P_iV_i}$$ ---
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