Organic Chemistry (8th Edition)

Published by Pearson
ISBN 10: 0321768418
ISBN 13: 978-0-32176-841-4

Chapter 6 - Alkyl Halides: Nucleophilic Substitution and Elimination - Study Problems - Page 280: 6-44 c

Answer

2-chloro-4,4-dimethylpentane reacts faster in SN2.

Work Step by Step

In 2-chloro-4,4-dimethylpentane, the carbon with the chlorine is further away from the bulky tert-butyl part of the molecule so that the nucleophile can attack the carbon easier.
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