Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 8 - Quantities in Chemical Reactions - Exercises - Problems - Page 277: 50

Answer

(a) $1\,mol\,TiCl_{4}$ (b) $4.5\,mol\,TiCl_{4}$ (c) $0.456\,mol\,TiCl_{4}$ (d) $7.9\,mol\,TiCl_{4}$

Work Step by Step

(a) Calculating how much product can be made based on the amount of each reactant, we have $2\,mol\,Ti\times\frac{1\,mol\,TiCl_{4}}{1\,mol\,Ti}=2\,mol\,TiCl_{4}$ $2\,mol\,Cl_{2}\times\frac{1\,mol\,TiCl_{4}}{2\,mol\,Cl_{2}}=1\,mol\,TiCl_{4}$ Since $2\,mol\,Cl_{2}$ makes the least amount of product, it is the limiting reactant. Theoretical yield is the maximum amount of product that can be made in a reaction based on the amount of limiting reactant. Therefore, theoretical yield= $1\,mol\,TiCl_{4}$. (b) Calculating how much product can be made based on the amount of each reactant, we have $5\,mol\,Ti\times\frac{1\,mol\,TiCl_{4}}{1\,mol\,Ti}=5\,mol\,TiCl_{4}$ $9\,mol\,Cl_{2}\times\frac{1\,mol\,TiCl_{4}}{2\,mol\,Cl_{2}}=4.5\,mol\,TiCl_{4}$ Since $9\,mol\,Cl_{2}$ makes the least amount of product, it is the limiting reactant. Theoretical yield= $4.5\,mol\,TiCl_{4}$ (c) Calculating how much product can be made based on the amount of each reactant, we have $0.483\,mol\,Ti\times\frac{1\,mol\,TiCl_{4}}{1\,mol\,Ti}=0.483\,mol\,TiCl_{4}$ $0.911\,mol\,Cl_{2}\times\frac{1\,mol\,TiCl_{4}}{2\,mol\,Cl_{2}}=0.456\,mol\,TiCl_{4}$ Since $0.911\,mol\,Cl_{2}$ makes the least amount of product, it is the limiting reactant. Theoretical yield= $0.456\,mol\,TiCl_{4}$ (d) Calculating how much product can be made based on the amount of each reactant, we have $12.4\,mol\,Ti\times\frac{1\,mol\,TiCl_{4}}{1\,mol\,Ti}=12.4\,mol\,TiCl_{4}$ $15.8\,mol\,Cl_{2}\times\frac{1\,mol\,TiCl_{4}}{2\,mol\,Cl_{2}}=7.9\,mol\,TiCl_{4}$ Since $15.8\,mol\,Cl_{2}$ makes the least amount of product, it is the limiting reactant. Theoretical yield= $7.9\,mol\,TiCl_{4}$
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