Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 18 - Organic Chemistry - Exercises - Problems - Page 689: 90

Answer

See the structure for each alcohol below:

Work Step by Step

Question a: β€˜hex’ means 6. So, no. of C in straight chain is 6. Step 1: Draw 6 C in a straight line and join them with single bond and numbering 1 to 6 from right to left. Step 2: ending name is 'anol'. It means there is an OH group and it will be at 1st position (because the name suggests 1-hexanol). Add OH group on no. 1 Carbon. Step 3: Fill the remaining valency of C with Hydrogen atom. Question b: Step 1 - 'hept' means 7. Draw 7 C in a straight line and join them with single bond and numbering the C from right to left. Step 2: Add methyl group on no. 3 and no.4 Carbon (as the name suggests 3,4-dimethyl) and add OH group on 2nd Carbon (as the name suggests 2-heptanol). Step 3 - Fill the remaining hands of C with H atom. Question c: Step 1 - 'oct' means 8. Draw 8 C in a straight line and join them with single bond and numbering the C atoms from right to left. Step 2: Add propyl group on no. 3 Carbon and OH group on no. 3 Carbon as substitute (as the name suggests 3-propyl-3-octanol). Step 3: Fill the remaining hands (valency) of C with H atom. Question d: Step 1 - 'hex' means 6. Draw 6 C in a straight line and join them with single bond and numbering them from right to left. Step 2: Add OH group on no. 1 Carbon and add two methyl group on no. 2 Carbon and add two ethyl group on no. 3 Carbon (as the name suggests 3,3-diethyl-2,2-dimethyl-1-hexanol). Step 3: Fill the remaining valency of C with H atom. See the steps in picturized form below:
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