Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 15 - Chemical Equilibrium - Exercises - Problems - Page 568: 78

Answer

(a) $Mg(OH)_2(s) \lt -- \gt Mg^{2+}(aq) + 2OH^-(aq)$ $K_{sp} = [Mg^{2+}][OH^-]^2$ (b) $FeCO_3(s) \lt -- \gt Fe^{2+}(aq) + CO_3^{2-}(aq)$ $K_{sp} = [Fe^{2+}][CO_3^{2-}]$ (c) $PbS(s) \lt -- \gt Pb^{2+}(aq) + S^{2-}(aq)$ $K_{sp} = [Pb^{2+}][S^{2-}]$ (d) $PbSO_4(s) \lt -- \gt Pb^{2+}(aq) + SO_4^{2-}(aq)$ $K_{sp} = [Pb^{2+}][SO_4^{2-}]$

Work Step by Step

The equation for when the compound dissolves in water: Reactant: Compound in solid form. Products: Aqueous ions that form the compound. The $K_{sp}$ expression have the pattern: $K_{sp} = \frac{[Products]}{[Reactants]}$ ** Do not forget to put the balancing coefficients as the exponents of the concentrations. But, since the reactant is solid, there will be only the multiplication of the ion concentrations.
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