Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 15 - Chemical Equilibrium - Exercises - Cumulative Problems - Page 570: 102

Answer

$ K_{sp} (NiCO_3) = (1.3 \times 10^{-7})$

Work Step by Step

1. Calculate the molar mass $(NiCO_3)$: 58.69* 1 + 12.01* 1 + 16* 3 = 118.7g/mol 2. Calculate the number of moles $(NiCO_3)$ $n(moles) = \frac{mass(g)}{mm(g/mol)}$ $n(moles) = \frac{ 0.042}{ 118.7}$ $n(moles) = 3.538\times 10^{- 4}$ 3. Find the concentration in mol/L $(NiCO_3)$: $3.538 \times 10^{-4}$ mol in 1L: $3.538 \times 10^{-4} M (NiCO_3)$ 4. Write the $K_{sp}$ expression: $ NiCO_3(s) \lt -- \gt 1Ni^{2+}(aq) + 1CO_3^{2-}(aq)$ $ K_{sp} = [Ni^{2+}]^ 1[CO_3^{2-}]^ 1$ 5. Determine the ion concentrations: $[Ni^{2+}] = [NiCO_3] * 1 = [3.538 \times 10^{-4}] * 1 = 3.538 \times 10^{-4}$ $[CO_3^{2-}] = [NiCO_3] * 1 = 3.538 \times 10^{-4}$ 6. Calculate the $K_{sp}$: $ K_{sp} = (3.538 \times 10^{-4}) \times (3.538 \times 10^{-4})$ $ K_{sp} = (1.3 \times 10^{-7})$
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