Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 13 - Solutions - Exercises - Problems - Page 483: 105

Answer

see solution

Work Step by Step

Given mass of solute, $C_6H_{12}O_6$= 55.8g mass of 1 mole of solute= 180g moles of solute = ((1/180)x55.8)= 0.3 moles Mass of solvent = 0.45 kg Molality= moles of solute/mass of solvent = 0.3moles/0.455 kg = 0.65 mol/kg dTb= (molality x Hvap ) Heat of vaporization= 0.512 C kg/mol Now dTb= 0.65 m x 0.512 Ckg/mol= 1.26 C Freezing point= 0-1.26C= -1.26C dTb= (molality x Hfusion ) Heat of fusion= 1.86 C kg/mol Now, dTb = 0.65 m x 1.86 Ckg/mol= 0.35 C Boiling point = 100+0.35 =100.35 C
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