Answer
Please see the work below.
Work Step by Step
We know that
a. Substance A has hydrogen bonding while substance B doesn't have hydrogen bonding. As hydrogen bonding is the stronger intermolecular force, hence the substance A having lower vapor pressure is in the flask on the right.
b. The amount of vapor present at $35C^{\circ}$ will be greater in both flasks than the amount present at $20C^{\circ}$, hence substance B will experience a larger increase.