Chemistry: The Molecular Nature of Matter and Change 7th Edition

Published by McGraw-Hill Education
ISBN 10: 007351117X
ISBN 13: 978-0-07351-117-7

Chapter 17 - Problems - Page 772: 17.75

Answer

(a) $$P_{O_2} = 4.0 \times 10^{-88}$$ (b) Since $Q_p \lt K_p$, the reaction will proceed to the right. (c) $$K_c = 6.1 \times 10^{88} $$

Work Step by Step

(a) - Write the Kp expression: $$K_p = \frac{1}{P_{O_2}}$$ - Substitute and find $P_{O_2}$ $$2.5 \times 10^{87} = \frac{1}{P_{O_2}}$$ $$P_{O_2} = \frac{1}{2.5 \times 10^{87}} = 4.0 \times 10^{-88}$$ (b) - Calculate Qp $$Q_p = \frac{1}{0.21} = 4.8$$ Since $Q_p \lt K_p$, the reaction will proceed to the right. (c) 1. Calculate $\Delta n$ (n is the amount of moles of gases): $$\Delta n = n_{products} - n_{reactants} = 0 - 1 = -1 $$ 2 . Calculate Kc: $$K_c = \frac{K_p}{(RT)^{\Delta n}} = \frac{( 2.5 \times 10^{87} )}{(0.0821 \times 298 )^{ -1 }}$$ $$K_c = 6.1 \times 10^{88} $$
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