Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 8 - Basic Concepts of Chemical Bonding - Exercises - Page 334: 8.14d

Answer

The Lewis symbol for $N^{3-}$ atom is seen in the diagram.

Work Step by Step

RULES TO WRITE LEWIS SYMBOL - Find out the number of valence electrons in the atom. - Write the element symbol and around it present each valence electron with one dot to the top, bottom, right or left of that symbol. - Spread out the dots as much as possible (so there would be minimum electron-electron repulsions), and no spots can hold over 2 electrons. 1) $N$ is in group 5A, so a neutral $N$ atom has 5 electrons in the outermost occupied shell. However, anion $N^{3-}$ added 3 more electrons to the outermost shell compared with its neutral $Sn$ atom. So, $N^{3-}$ has 8 electrons in the outermost occupied shell. That means $N^{3-}$ has 8 valence electrons. The Lewis symbol of $N^{3-}$ would have 8 dots. 2) 8 dots is the maximum number of dots in a Lewis symbol (for now). Since each spot can hold no more than 2 dots, 8 dots would spread evenly into 4 spots, so each spot holds 2 dots. Eventually, all 4 spots are occupied by 2 dots.
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