Chemistry 9th Edition

Published by Cengage Learning
ISBN 10: 1133611095
ISBN 13: 978-1-13361-109-7

Chapter 15 - Acid-Base Equilibria - Exercises - Page 751: 32

Answer

The pH of this buffer is equal to $3.37$

Work Step by Step

1. Calculate the pKa Value $pKa = -log(Ka)$ $pKa = -log( 7.2 \times 10^{- 4})$ $pKa = 3.143$ 2. Check if the ratio is between 0.1 and 10: - $\frac{[Base]}{[Acid]} = \frac{1}{0.6}$ - 1.667: It is. 3. Check if the compounds exceed the $K_a$ by 100 times or more: - $ \frac{1}{7.2 \times 10^{-4}} = 1389$ - $ \frac{0.6}{7.2 \times 10^{-4}} = 833.3$ 4. Using the Henderson–Hasselbalch equation: $pH = pKa + log(\frac{[Base]}{[Acid]})$ $pH = 3.143 + log(\frac{1}{0.6})$ $pH = 3.143 + log(1.667)$ $pH = 3.143 + 0.2218$ $pH = 3.365 \approx 3.37$
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