Chemistry 9th Edition

Published by Cengage Learning
ISBN 10: 1133611095
ISBN 13: 978-1-13361-109-7

Chapter 14 - Acids and Bases - Exercises - Page 704: 75

Answer

The $K_a$ for that weak acid is equal to $1.4 \times 10^{-4}$.

Work Step by Step

1. Drawing the equilibrium (ICE) table, we get these concentrations at equilibrium: For the reaction: $HA(aq) + H_2O(l) \lt -- \gt A^-(aq) + H_3O^+(aq) $ Remember: Reactants get a '-x', and products get a '+x' The initial concentration of $A^-$ is : 0 M, and the same for $[H_3O^+]$ is $\approx$ 0 M -$[H_3O^+] = [A^-] = 0 + x = x$ -$[HA] = [HA]_{initial} - x$ 2. The percent dissociation formula is: $\% dissociation = \frac{x}{[HA]_{initial}} \times 100\%$ $3.0\% = \frac{x}{0.15M} \times 100\%$ - Solve for "x: $\frac{3.0\% \times 0.15M}{100\%} = x$ $x = 4.5 \times 10^{-3}M$ 3. Now, use the Ka value and equation to find the 'x' value. $K_a = \frac{[H_3O^+][A^-]}{ [HA]}$ $K_a = \frac{(x)(x)}{[HA]_{initial}-x}$ $K_a = \frac{(4.5 \times 10^{-3})^2}{0.15-4.5 \times 10^{-3}} = 1.4 \times 10^{-4}$
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