Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 24 - Organic Chemistry - Questions & Problems - Page 1051: 24.5

Answer

Since C=C bonds involve $\pi$ orbitals, rotation is restricted because the orientation of the $\pi$ orbitals are definite; thus excessive rotation will destroy or significantly warp the bond-forming orbitals, a process which is energetically unfavorable and requires additional input of energy into the system.

Work Step by Step

Since C=C bonds involve $\pi$ orbitals, rotation is restricted because the orientation of the $\pi$ orbitals are definite; thus excessive rotation will destroy or significantly warp the bond-forming orbitals, a process which is energetically unfavorable and requires additional input of energy into the system.
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