Anatomy & Physiology: The Unity of Form and Function, 7th Edition

Published by McGraw-Hill Education
ISBN 10: 0073403717
ISBN 13: 978-0-07340-371-7

Chapter 2 - Section 2.1 - Study Guide - Assess Your Learning Outcomes - Page 74: 9

Answer

Isomers are molecules that have the same molecular formula, which means they contain the same types and numbers of atoms but have different structural arrangements or spatial orientations of those atoms. Isomers can resemble each other in terms of their molecular composition but differ in their chemical or physical properties due to their distinct structural arrangements. There are two main types of isomerism: structural (or constitutional) isomerism and stereoisomerism. **Structural Isomerism**: Structural isomerism, also known as constitutional isomerism, occurs when isomers have different connectivity of atoms in their molecular structures. In other words, they have different arrangements of atoms or bonds. There are several types of structural isomers, including: 1. **Chain Isomers**: Chain isomers have different arrangements of the carbon skeleton. For example, butane (C4H10) and isobutane (C4H10) are chain isomers. Butane has a linear carbon chain, while isobutane has a branched carbon chain. 2. **Position Isomers**: Position isomers have the same carbon skeleton but differ in the location of functional groups or substituents on that skeleton. An example is 1-propanol (CH3CH2CH2OH) and 2-propanol (CH3CHOHCH3). They both have a three-carbon chain, but the hydroxyl group is attached to different carbon atoms. 3. **Functional Group Isomers**: Functional group isomers have the same molecular formula but contain different functional groups. For instance, ethanol (CH3CH2OH) and dimethyl ether (CH3OCH3) are functional group isomers. Ethanol contains an -OH group, while dimethyl ether has an oxygen atom bonded to two methyl groups. **Stereoisomerism**: Stereoisomerism arises when isomers have the same molecular connectivity but differ in the spatial arrangement of their atoms. There are two main types of stereoisomerism: 1. **Geometric (Cis-Trans) Isomerism**: Geometric isomerism occurs in compounds with double bonds or rings that restrict the rotation of atoms around a bond. In cis-trans isomerism, atoms or groups can be arranged differently on either side of the restricted bond. For example, in the molecule 2-butene (C4H8), cis-2-butene has two similar groups on the same side of the double bond, while trans-2-butene has them on opposite sides. 2. **Optical Isomerism (Enantiomerism)**: Optical isomerism arises in molecules with chiral centers, which are carbon atoms bonded to four different substituents. Enantiomers are mirror-image isomers that cannot be superimposed onto each other. They have the same connectivity but differ in their spatial arrangement. A well-known example is L- and D-amino acids, which are mirror-image forms of each other. In summary, isomers resemble each other in that they have the same molecular formula but differ in their structural arrangements (structural isomerism) or spatial orientations (stereoisomerism). The differences in these arrangements or orientations can lead to variations in the chemical and physical properties of isomers, making them distinct molecules with potentially different reactivity, biological activity, and physical characteristics.

Work Step by Step

Isomers are molecules that have the same molecular formula, which means they contain the same types and numbers of atoms but have different structural arrangements or spatial orientations of those atoms. Isomers can resemble each other in terms of their molecular composition but differ in their chemical or physical properties due to their distinct structural arrangements. There are two main types of isomerism: structural (or constitutional) isomerism and stereoisomerism. **Structural Isomerism**: Structural isomerism, also known as constitutional isomerism, occurs when isomers have different connectivity of atoms in their molecular structures. In other words, they have different arrangements of atoms or bonds. There are several types of structural isomers, including: 1. **Chain Isomers**: Chain isomers have different arrangements of the carbon skeleton. For example, butane (C4H10) and isobutane (C4H10) are chain isomers. Butane has a linear carbon chain, while isobutane has a branched carbon chain. 2. **Position Isomers**: Position isomers have the same carbon skeleton but differ in the location of functional groups or substituents on that skeleton. An example is 1-propanol (CH3CH2CH2OH) and 2-propanol (CH3CHOHCH3). They both have a three-carbon chain, but the hydroxyl group is attached to different carbon atoms. 3. **Functional Group Isomers**: Functional group isomers have the same molecular formula but contain different functional groups. For instance, ethanol (CH3CH2OH) and dimethyl ether (CH3OCH3) are functional group isomers. Ethanol contains an -OH group, while dimethyl ether has an oxygen atom bonded to two methyl groups. **Stereoisomerism**: Stereoisomerism arises when isomers have the same molecular connectivity but differ in the spatial arrangement of their atoms. There are two main types of stereoisomerism: 1. **Geometric (Cis-Trans) Isomerism**: Geometric isomerism occurs in compounds with double bonds or rings that restrict the rotation of atoms around a bond. In cis-trans isomerism, atoms or groups can be arranged differently on either side of the restricted bond. For example, in the molecule 2-butene (C4H8), cis-2-butene has two similar groups on the same side of the double bond, while trans-2-butene has them on opposite sides. 2. **Optical Isomerism (Enantiomerism)**: Optical isomerism arises in molecules with chiral centers, which are carbon atoms bonded to four different substituents. Enantiomers are mirror-image isomers that cannot be superimposed onto each other. They have the same connectivity but differ in their spatial arrangement. A well-known example is L- and D-amino acids, which are mirror-image forms of each other. In summary, isomers resemble each other in that they have the same molecular formula but differ in their structural arrangements (structural isomerism) or spatial orientations (stereoisomerism). The differences in these arrangements or orientations can lead to variations in the chemical and physical properties of isomers, making them distinct molecules with potentially different reactivity, biological activity, and physical characteristics.
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