Answer
No, the percentages do not have a sum of 100%.
Work Step by Step
Let us round each of the percentages down--to the closest 10%.
Google: 40%
Facebook: 20%
Yahoo!: 20%
YouTube: 20%
Windows Live: 10%
Wikipedia: 10%
$40+20+20+20+10+10=120$
People are not limited to one website per day--they can visit as many websites as they wish. People marked (on the survey) that they visited multiple websites on a day.