Materials Science and Engineering: An Introduction

Published by Wiley
ISBN 10: 1118324579
ISBN 13: 978-1-11832-457-8

Chapter 14 - Polymer Structures - Questions and Problems - Page 577: 14.3

Answer

$DP = 4,847.78 \approx 4,848$

Work Step by Step

Given: The number-average molecular weight of a polystyrene is 500,000 g/mol. Required: degree of polymerization Solution: From Table 14.3, each repeat unit consists of 7 hydrogens and 8 carbons. Computing the repeat unit molecular weight: $m = 8(A_{C}) + 7(A_{H})= 8(12.011 g/mol) + 7(1.008 g/mol) = 103.14 g/mol$ Using Equation 14.6: $DP = \frac{M_{n}}{m} = \frac{500,000 g/mol}{103.14 g/mol} = 4,847.78 \approx 4,848$
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