Materials Science and Engineering: An Introduction

Published by Wiley
ISBN 10: 1118324579
ISBN 13: 978-1-11832-457-8

Chapter 12 - Structures and Properties of Ceramics - Questions and Problems - Page 507: 12.33a

Answer

For a Cu2+O2- compound in which a small fraction of the copper ions exist as Cu+, there is one less positive charge introduced (or one more negative charge) for each Cu+ formed. In order to maintain the charge neutrality, addition of positive charge or subtraction of a negative charge may be needed. This may be accomplished either by creating Cu2+ interstitials or O2- vacancies.

Work Step by Step

For a Cu2+O2- compound in which a small fraction of the copper ions exist as Cu+, there is one less positive charge introduced (or one more negative charge) for each Cu+ formed. In order to maintain the charge neutrality, addition of positive charge or subtraction of a negative charge may be needed. This may be accomplished either by creating Cu2+ interstitials or O2- vacancies.
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