Answer
You can use both symbols at any time - they mean nothing unless you officially register a trademark or copyright.
Work Step by Step
This is illuminated by U.S. law.
Understanding Business, 10th Edition
by Nickels, William G.; McHugh, James M.; McHugh, Susan M.
Published by
McGraw-Hill Education
ISBN 10:
007352459X
ISBN 13:
978-0-07352-459-7
Bonus Chapter A - Working within the Legal Environment - Taking it to the Net - Page A-22: 2
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